Search results for " Quadrupole interactions"

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Dynamics of hyaluronan aqueous solutions as assessed by fast field cycling NMR relaxometry.

2010

Fast field cycling (FFC) NMR relaxometry has been used to study the conformational properties of aqueous solutions of hyaluronan (HYA) at three concentrations in the range 10 to 25 mg mL(-1). Results revealed that, irrespective of the solution concentration, three different hydration layers surround hyaluronan. The inner layer consists of water molecules strongly retained in the proximity of the HYA surface. Because of their strong interactions with HYA, water molecules in this inner hydration layer are subject to very slow dynamics and have the largest correlation times. The other two hydration layers are made of water molecules which are located progressively further from the HYA surface.…

RelaxometryAqueous solutionMagnetic Resonance SpectroscopyField cyclingChemistrySettore AGR/13 - Chimica AgrariaDynamics (mechanics)Analytical chemistryWaterBiochemistryAnalytical ChemistryIntramolecular forceQuadrupoleMolecular motionCarbohydrate ConformationMoleculeFFC-NMR Relaxometry Correlation time Quadrupole interactions Hydration layerHyaluronic AcidAnalytical and bioanalytical chemistry
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